Please pass me the book whose(of which )cover is green?能不能用that代替whose ,为什么?

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Please pass me the book whose(of which )cover is green?能不能用that代替whose ,为什么?

不能.
whose在从句中作定语(书的封面),whose可以指人或物.
如:Mary is the girl whose father died last week.
I like the room whose window faces the south.

不能,从句中不缺少成分。

不可以,如果用that那么从句里就有两个主语了,重复了
不过可以用which
Please pass me the book which cover is green?